Bioenz.com.au

Material Safety Data Sheet
Issue date: September 2007/ Expiry Date: September 2012 LIQUE-FLY

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: LIQUE-FLY
Synonym:

Use: LIQUE – FLY is non flammable water based odourless FLYSPRAY, formulated to control flies, mosquitoes, silverfish, carpet
beetles, cockroaches, ants and other crawling insects.
MILESTONE CHEMICALS AUSTRALIA PTY LTD
115 NORTHERN ROAD,
WEST HEIDELBERG, VIC, 3081
Tel: (03) 9450 4555
Fax: (03) 9457 5518
Emergency Advice All Hours:
Chief Chemist
Tel: (03) 9450 4555
Monday 8:00 a.m. - Friday 6:00 p.m.
Poisons Information Centre
Phone Australia: 13 1126

2. HAZARDS IDENTIFICATION
HAZARDOUS ACCORDING TO EU CRITERIA
Hazard Category: Irritant (Xi)
Hazard Classification: HAZARDOUS SUBSTANCE, NON-DANGEROUS GOOD
RISK PHRASES
R36
May cause long term adverse effects in the aquatic environment. SAFETY PHRASES
S2
Keep away from food, drink and animal feeding stuffs. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of insufficient ventilation, wear suitable respiratory protection. If swallowed, do not induce vomiting; Seek medical advice immediately and show this container or label. Poison Schedule: S5 [Aust]
This material is a Scheduled S5 Poison and must be stored, handled and used according to the appropriate regulations.
Warning Statement:
None Recommended.
3. COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE NAME
Proportion
CAS Number
WATER AND OTHER NON-HAZARDOUS SUBSTANCES 30 to 60% This product contains: PERMETHRIN 7.5 g/LT DIETHYLENE GLYCOL MONOBUTYL ETHER 350 g/LT All other ingredients not hazardous according to EU Criteria. Material Safety Data Sheet
Issue date: September 2007/ Expiry Date: September 2012 LIQUE-FLY
4. FIRST AID MEASURES
Swallowed:
If swallowed, DO NOT induce vomiting. Give a glass of water to drink. Seek urgent medical assistance.

Eye:
If material is splashed into eyes, immediately, flush with plenty of water for 15 minutes, ensuring eye lids are held open. If irritation
persists transport to hospital or doctor.

Skin:
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with soap and water. If irritation
persists transport to hospital or doctor.

Inhaled:
Move victim to fresh air. Apply resuscitation if victim is not breathing.

First Aid Facilities:
Eye wash fountain, safety shower and normal wash room facilities.
Advice to Doctor:
Treat symptomatically.

In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000
5. FIRE-FIGHTING MEASURES
Fire/Explosion Hazard
If safe to do so, move undamaged containers from fire area.
Hazardous Decomposition Products: Decomposes on heating emitting oxides of carbon.
Fire Fighting Procedures: Fire fighters to wear Self-contained breathing apparatus (SCBA) in confined spaces, in oxygen deficient
atmospheres or if exposed to products of decomposition. Full protective clothing is also recommended.
Extinguishing Media: Use extinguishing media suitable for surrounding fire situation.
HAZCHEM CODE: None allocated [Aust]
FLAMMABILITY
This material is not a flammable or combustible liquid.
6. ACCIDENTAL RELEASE MEASURES
Material may be slippery when spilt. Walk cautiously. Ventilate area. Wear protective equipment to prevent skin and eye contact, as
outlined under personal protection in this MSDS. Bund area using sand or soil - to prevent run off into drains and waterways. Use
absorbent (soil, sand, vermiculite or other inert material). Collect and seal in properly labelled containers for disposal.

7. HANDLING AND STORAGE
Store in a cool place and out of direct sunlight. Store away from sources of heat or ignition. Store away from oxidizing agents. Keep
containers closed, when not using the product. Store in original packages as approved by manufacturer.


Material Safety Data Sheet
Issue date: September 2007/ Expiry Date: September 2012 LIQUE-FLY

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards
No exposure standards are available for this product, however, the following exposure standards have been assigned by [NOHSC] to the
following components of the product:
WATER SOLUBLE PERMETHRIN CONCENTRATE
No Exposure details available
ETHANOL
(Worksafe Australia)
[TWA]1,000 ppm

References: H
(ACGIH)
[TWA]1,000 ppm
DIETHYLENE GLYCOL MONOBUTYL ETHER
No exposure standards have been assigned by the National Occupational Health & Safety Commission (NOHSC)
WATER AND OTHER NON-HAZARDOUS SUBSTANCES
No Exposure details available
Engineering Controls
Maintain adequate ventilation at all times. In most circumstances natural ventilation systems are adequate unless the material is heated,
reacted or otherwise changed in some type of chemical reaction, then the use of a local exhaust ventilation system is recommended.
Personal Protection Equipment
This product is hazardous and poisonous. The following protective equipment should be worn when handling product directly.
GLOVES: PVC or natural rubber.
EYES: Chemical goggles.
RESPIRATORY PROTECTION: Avoid breathing of vapours/gases. Select and use respirators in accordance with AS/NZS 1715/1716.
The use of a P1 dust mask (disposable) or with replaceable filters is recommended. Filter capacity and respirator type depends on
exposure levels and type of contaminant. If entering spaces where the airborne concentration of a contaminant is unknown then the use
of a Self-contained breathing apparatus (SCBA) with positive pressure air supply complying with AS/NZS 1715 / 1716, or any other
acceptable International Standard is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Boiling Point Melting Point:
Vapour Pressure:
Specific Gravity:
Flash Point:
Flammability Limits:
Solubility in Water:

Other Properties
pH AS IS : 6.0 - 7.0
Odour : Typical fly spray
10. STABILITY AND REACTIVITY
STABILITY:
Stable under normal conditions of use.
HAZARDOUS DECOMPOSITION PRODUCTS:
Emits smoke and fumes when heated to decomposition.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
Strong alkalis, acids, oxidizing agents.
CONDITIONS TO AVOID:
Heat, flames, ignition sources and incompatibles.
Material Safety Data Sheet
Issue date: September 2007/ Expiry Date: September 2012 LIQUE-FLY

11. TOXICOLOGICAL INFORMATION
No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and the product
label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE HEALTH EFFECTS:
Swallowed:
May cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and lips and pains in
the stomach, which may lead to nausea, vomiting and diarrhoea.
Eye:
Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon duration of exposure,
eye damage may occur.
Skin:
May cause irritation to the skin, with effects including; Redness and itchiness.
Inhaled:
May cause irritation to the nose, throat and respiratory system with effects including: Dizziness, headache and loss of co-ordination.

Chronic:
Prolonged or repeated skin contact may lead to dermatitis.
Prolonged contact may cause severe eye irritation and some form of permanent eye damage may occur.
Toxicological Data:
There is no other toxicological information available for this product.

12. ECOLOGICAL INFORMATION
Ecotoxity:
See below.
Mobility:
Clear watery liquid that is miscible with water.
Persistence / Degradability:
Inherently Biodegradable.
Chemical Fate Information:
This substance is Very Toxic to aquatic organisms
This substance may cause long term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS
Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Normally suitable for disposal by
approved waste disposal agent.
14. TRANSPORT INFORMATION
Road Transport
UN Number: None allocated
Proper Shipping Name: None allocated
Dangerous Goods Class: None allocated
Packing Group: None allocated
Label: Irritant (Xi)
Air Transport
UN Number: None allocated
Proper Shipping Name: None allocated
Dangerous Goods Class: None allocated
Packing Group: None allocated
Label: Irritant (Xi)
Sea Transport
UN Number: None allocated
Proper Shipping Name: None allocated
Dangerous Goods Class: None allocated
Packing Group: None allocated
Label: Irritant (Xi)
Material Safety Data Sheet
Issue date: September 2007/ Expiry Date: September 2012 LIQUE-FLY

15. REGULATORY INFORMATION
Poison Schedule: S5 [Aust]

Inventory Status:
Inventory

16. OTHER INFORMATION
Date of Preparation:
Issue date: 25/09/07
Supersedes: 13/09/07
Reasons for Update:
New Product.
Address and phone number.
ASCC (Australian Safety and Compensation Council) HSIS (Hazardous Substances Information System) Consolidated List of
Designated Hazardous Substances to supersede [NOHSC: 10005(1999)].
Disclaimer Statement.
Key Legend Information:
NOHSC - National Occupational Health & Safety Commission {Formerly Worksafe}[Aust]
ASCC – Australian Safety and Compensation Council {Formerly NOHSC}
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
EPA - Environmental Protection Agency [Int]
NIOSH - National Institute for Occupational Safety and Health [US]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]
AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]
IATA - International Aviation Transport Authority [Int]
ICAO - International Civil Aviation Organization [Int]
IMO - International Maritime Organisation. [Int]
IMDG - International Maritime Dangerous Goods [Int]
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the classification and
labelling of Chemicals. [Int]
EU - European Union
[Aust/NZ] = Australian New Zealand
[Int] = International
[US] = United States of America

Removal of the heading of Poison Schedule [Aust], in section 3 and 15 of this Material Safety Data Sheet (MSDS) makes this a valid
health and safety document in other international jurisdictions/countries. For full compliance please contact your Federal, State or Local
regulators for further information.

Disclaimer
This MSDS summarises our best knowledge of the health and safety hazard information available on the product and the measures to be
used to handle and use the product safely. Each user should read this MSDS and consider the information in connection with the way the
product is intended to be handled or used.

Milestone Chemicals Australia Pty Ltd will not accept any responsibility for any changes made to its M.S.D.S by any other person or
organisation.

Principal References:
Information supplied by manufacturer, reference sources including the public domain.
END OF MSDS

Source: http://www.bioenz.com.au/MSDS/LIQUE-FLY.pdf