MATERIAL SAFETY DATA SHEET 1. CHEMICAL NAME Product Name: Chemical Name: Emergency Telephone: Application: Manufacturer: 2. COMPOSTION/INFORMATION ON INDREGIENTS Component 3. HAZARDS IDENTIFICATION Emergency Overview:
WARNING! Dust may be irritation to eyes and upper respiratory
tract. Fine dust clouds may form explosive mixtures with air. Highly toxic to fish and aquatic invertebrates. May cause sensitization by skin contact. May cause alcohol intolerance.
Causes mild eye irritation. Mild Eye Irritation: signs/symptoms
can include redness, swelling, pain and tearing.
May cause an allergic skin reaction. May be absorbed through
the skin and product effects similar to those caused by inhalation and/or ingestion. May cause skin defatting with prolonged exposure.
Inhalation: Exposure to dust particles generated from this material may
cause irritation of the respiratory tract. Inhalation may cause alcohol intolerance.
May cause alcohol intolerance (Antabuse Effect). May cause
headache, dizziness, nausea, vomiting, gastrointestinal irritation.
4. FIRST AID MEASURES
In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
in case of contact, immediately flush skin with plenty of soap and water for at
least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse. Get medical attention if irritation persists.
Remove person to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, get immediate medical attention.
If swallowed, call a physician immediately. Only induce vomiting at the
instruction of a physician. Never give anything by mount to an unconscious person.
Note to Physician:
Treat symptomatically. Exposure by ingestion, inhalation or skin absorption may cause alcohol intolerance. (Antabuse Effect).
5. FIRE FIGHTING MEASURES Flash Point (°F/C): Flash Point Method: Auto Ignition Temp (°F/C): Lower Explosion Limit (LEL): Upper Explosion Limit (UEL): Extinguishing Media:
Use water fog, carbon dioxide, foam or dry chemical
Special Exposure Hazards:
Fight fire from a safe distance and from a protected
location. Use water spry to cool fire exposed surfaces. Decomposition in fire may product toxic gases. Do not allow runoff to enter water ways.
Special Protective Equipment:
Full protective clothing and approved self-contained
breathing apparatus required for fire fighting personnel.
Unusual Fire/Explosions Hazards:
Toxic emissions may result if product is involved in a fire
Dust Class = ST 1. Minimum Ignition Energy [MIE] = < 10 mJ. Kst = 150 bar.m/sec Rmax = 552 bar/s Pmax = 6.8 bar
6. ACCIDENT RELEASE MEASURES Spill Procedures:
Wear protective equipment specified. Avoid the
generation of dust. Sweep, vacuum, or shovel and place into closable container for disposal.
Procedure for Cleaning/ Absorption: Isolate area and remove sources of friction, impact, heat,
low level electrical current and RF energy. Scoop up and remove solids. Do NOT spread spilled product with water.
CERCLA Reportable Quantity: 7. HANDLING & STORAGE Handling:
Avoid contact with eyes, skin and clothing. Avoid generating or breathing dust.
Wash thoroughly with soap and water after handling. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Reclose containers of unused product. Keep containers tightly closed when not in use. Do not refuse this container.
Store closed containers in a cool, dry, well-ventilated area. Store away from
strong oxidizing materials. Avoid exposure to direct sunlight.
8. EXPORUSRE CONTROLS & PERSONAL PROTECTION Eye Protection:
Wear safety glasses or goggles to protect against exposure.
Normal work coveralls. Launder contaminated clothing before reuse.
Use gloves as a standard industrial handling procedure. Appropriate
chemical resistant gloves should be worn.
Use in a well-ventilated area. Use approved NIOSH respiratory protection if TLV exceeded or if overexposure is likely. Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure.
Ventilation: General; local exhaust ventilation as necessary to control any air
contaminants to within their exposure limits during the use of this product.
Airborne Exposure Limits:
OSHA PEL 8-hr TWA: None Established. NIOSH REL/8-Hr TWA: 2mg/m³. ACGIH TLV/8-Hr TWA: 2mg/m³.
9. PHSICAL & CHEMICAL PROPERTIES Appearance: Specific Gravity: Density: Bulk Density: Melting Point (°F/C): Boiling Point (°F/C): Vapor Pressure: Vapor Density (Air=1): % Volatile by Volume: Soluble in Water: Other Solubility:
Soluble in: Benzene, Carbon Disulfide, Organic liquids, including
Viscosity: Other Data: Molecular Weight: Molecular Formula: 10. STABILITY & REACTIVITY Chemical Stability:
Stable when stored at room temperature in closed, original
container. Stable under normal conditions or handling, use and transportation.
Hazardous Polymerization: Will Not Occur Conditions to Avoid: Materials to Avoid:
Avoid contact with acidic, basic or oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur
Additional Guidelines: 11. TOXICOLOGICAL INFORMATION Acute Oral LD50 (mg/kg): Acute Dermal LD50 (mg/kg): Acute Inhalation LC50 (mg/l): Target Organs / Principle Routes of Exposure: Dermal- skin. Inhalation Eye Contact:
Causes mild eye irritation. Mild Eye Irritation: signs/symptoms can
include redness, swelling, pain and tearing.
may cause an allergic skin reaction. May be absorbed through the skin
and product effects similar to those caused by inhalation and/or ingestion. May cause skin defatting with prolonged exposure.
Exposure to dust particles generated from this material may cause
irritation of the respiratory tract. Inhalation may cause alcohol intolerance.
May cause alcohol intolerance (Antabuse Effect). May cause headache,
dizziness, nausea, vomiting, gastrointestinal irritation.
Alcohol consumption problems: IMPORTANT NOTE: Perkacit TETD and the prescription alcohol aversion drug “Antabuse” are the same chemical.
This product, or one of its ingredients present at 0.1% or more, is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA. NOTE: May react with nitrosating agents during rubber vulcanization to form nitrosamines. Some nitrosamines are suspect human carcinogens.
Other Information: Ingestion of the product may result vomiting. Primary Irritation Effect: Carcinogenicity:
Negative in standard tests using bacteria and/or yeast cells.
Genotoxicity: Reproductive/Developmental Toxicity:
No evidence of teratogenicity in animal studies using rates, mice and or hamsters.
12. ECOLOGICAL INFORMATION Acute Fish Toxicity: Acute Crustaceans Toxicity: Acute Algae Toxicity: Octanol/Water Coefficient: Chemical Fate Information: Other Information: 13. DISPOSAL CONSIDERATIONS Disposal of Waste Method: This product, if disposed as received, in a non-hazardous waste.
Bury in a licensed landfill or burn in an approval incinerator according to federal, state, and local regulations. Federal, state and local disposal laws and regulations will determine the proper waste
requirements are dependent on the hazard classification and will vary by location and the type of disposal selected.
Contaminated Packaging: If empty container retains product residues, all label precautions
must be observed. Transport with all closures in place. Return for reuse or dispose according to national and local regulations. DO NOT reuse container. Dispose of container according to national or local regulations.
14. TRANSPORTATION INFORMATION DOT Reportable Quantity (lbs): ICAO/IATA:
UN3077 Environmentally Hazardous Substance, Solid
N. O.S. (Tetraethylthiuram Disulfide), 9, III. Subject to ICAO/IATA ENVIROMENTALLY HAZARDOUS SUBSTANCE marking requirement [IATA 220.127.116.11]
UN3077 Environmentally Hazardous Substance, Solid N.
O.S. (Tetraethylthiuram Disulfide), 9, III, Marine
TDG (Canada): Remarks:
Not listed in DOT Marine Pollutant list Appendix B to
172.101, therefore not regulated as Marine Pollutant by
15. REGULARTORY INFORMATION Worldwide Inventory Status USA (TSCA): Canada (DSL): Canada (NDSL): Europe (EINECS/ELINCS): Listed Japan (ENCS): Listed Korea (ECL): Listed Australia (AICS): Listed New Zealand (NZ): Listed Philippines (PICCS): Listed China (CLECS): Listed US Regulatory Rules SARA 302: SARA 311/312 Hazard Categories: SARA 313 Chemical: RCRA Status: Other Regulations California Proposition 65: New Jersey Right to Know: Pennsylvania Right to Know: Florida Right to Know: Minnesota Right to Know: Massachusetts Right to Know: FDA Status 21 CFR:
Regulated for use under the following sections of 21 CFR:
177.2600 Rubber Articles Intended for Repeated use in food Contact. 175.105 Components of Adhesives. IMPORTANT NOTE: FDA information applies to the –pdr and –pdr-s product forms (no dedusting additive) ONLY.
Canadian Regulations WHMIS Hazard Class:
D2B TOXIC MATERIALS/Materials Causing Other Toxic
16. OTHER INFORMATION Hazard Rating Systems: HMIS Classification: NFPA Rating: The following has been revised since the last issue of this MSDS: Updated transport information. Additional Information: WHMIS Ingredient Disclosure List (Canada): WHMIS Concentration threshold =1%. This product has been classified and appears on the Mexico Hazard Identification Guidance List. Important Note:
This information is furnished without warranty, expressed or implied as
to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. This information may not be valid under all conditions not if this material is used in combination with other materials or in any process. Final determination of suitability of any material is sole responsibility of the user.
M. Shima, K. Yohdou, M. Yamaguchi, Y. Kimura, S. Adachi, R. Matsuno Effects of medium chain fatty acids and their acylglycerols on the transport of penicillin V across Caco2 cell monolayers Biosci. Biotech. Biochem., 61(7), 1150−1155, 1997. M. Shima, Y. Kimura, S. Adachi, R. Matsuno The relationship between transport-enhancement effects and cell viability by capric acid sodium salt, monocap