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Material Safety Data Sheet
Product Name DURAFLOOR X PRIMER HARDENER
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name
Company Name
Parchem Construction Supplies Pty Ltd (ABN 80 069 961 968) Emergency Tel.
Telephone/Fax
Recommended Use
Aliphatic amine component of a two pack epoxy floor coating.
Other Information
This MSDS summarises at the date of issue our best knowledge of the health and safety hazard information of the product, and in particular how to safely handle and use the product in the workplace. Since Parchem Construction Supplies Pty Ltd cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available upon request.
www.parchem.com.au 2. HAZARDS IDENTIFICATION
Classification
DANGEROUS GOODS.
Hazard classification according to the criteria of NOHSC.
Dangerous goods classification according to the Australia Dangerous Goods Code.
Risk Phrase(s)
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrase(s)
S2 Keep out of reach of children. S20/21 When using, do not eat, drink or smoke. S23(2) Do not breathe vapour. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of waterS36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheet.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Proportion
4. FIRST AID MEASURES
Inhalation
If inhaled, remove affected person from contaminated area. Apply artificial respiration if not breathing. Seek medical attention.
Ingestion
Do not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.
Remove all contaminated clothing. Wash gently and thoroughly with water and non-abrasive soap for 15 minutes. Ensure contaminated clothing is washed Material Safety Data Sheet
Product Name DURAFLOOR X PRIMER HARDENER
before re-use or discard. Seek medical attention.
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Seek immediate medical attention.
First Aid Facilities
Eye wash fountain, safety shower and normal washroom facilities.
Advice to Doctor
Other Information
For advice in an emergency, contact a Poisons Information Centre (Phone Australia 13 1126) or a doctor at once.
5. FIRE FIGHTING MEASURES
Suitable
Use carbon dioxide, dry chemical, foam, water mist or water spray.
Extinguishing Media
Hazards from

Under fire conditions this product may emit toxic and/or irritating fumes and Combustion
gases including carbon monoxide, carbon dioxide, nitrogen oxides and ammonia.
Products
Specific Hazards

Combustible liquid. This product will readily burn under fire conditions.
Hazchem Code
Precautions in
Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated connection with Fire
in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-exposed containers. Fight fire from safe location. This product should be prevented from entering drains and watercourses.
Other Information
6. ACCIDENTAL RELEASE MEASURES
Emergency
Wear appropriate personal protective equipment and clothing to prevent Procedures
exposure. Extinguish or remove all sources of ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non-combustible material onto spillage. Use clean non-sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water authorities and EPA in accordance with local regulations.
7. HANDLING AND STORAGE
Precautions for Safe
Corrosive and combustible liquid. Attacks skin and eyes. May produce severe Handling
burns. Wear suitable protective clothing, gloves and eye/face protection when mixing and using. Use in designated areas with adequate ventilation. Avoid breathing in vapours, mist or fumes. Keep containers closed when not in use. Ensure a high level of personal hygiene is maintained when using this product, that is, always wash hands after handling, and before eating, drinking, smoking or using the toilet facilities. Do not use near ignition sources. Do not pressurise, cut, heat or weld containers as they may contain hazardous. Prevent the build up of mists or vapours in the work atmosphere. Keep containers sealed when not in use.
Conditions for Safe
Corrosive and combustible liquid for storage and handling purposes. Keep tightly closed in a dry, cool, well-ventilated area, out of direct sunlight. Provide a catch-tank in a bunded area. Avoid sparks, flames and other ignition sources. Store away from incompatible materials. Do NOT pressurise, cut, heat or weld containers as they may contain hazardous residues. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. For information on the design of the store-room reference should be made to Australian Standard AS1940 - The storage and handling of flammable and combustible liquids and AS 3780-2008 The storage and handling of corrosive substances. Reference should also be made to all Local, State and Federal regulations.
Material Safety Data Sheet
Product Name DURAFLOOR X PRIMER HARDENER
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
National Exposure
No value is assigned for this specific material by the National Occupational Standards
Health and Safety Commission (NOHSC) Australia, however the available exposure limits on the ingredients as provided by NOHSC are as follows:Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³m-xylenediamine - 0.1 (peak limit) - - SkTWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day week.
STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday.
Peak Limitation: A ceiling concentration which should not be exceeded over a measurement period which should be as short as possible but not exceeding 15 minutes.
'Sk' Notice: Absorption through the skin may be a significant source of exposure. The exposure standard is invalidated if such contact should occur.
Biological Limit
Values
Engineering

Provide sufficient ventilation to keep airborne levels below the exposure Controls
limits. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a flameproof exhaust ventilation system is required. Refer to AS 1940 - The storage and handling of flammable and combustible liquids and AS/NZS 2430.3.1:1997: Classification of hazardous areas - Examples of area classification - General, for further information concerning ventilation requirements.
Respiratory
If engineering controls are not effective in controlling airborne exposure Protection
then an approved respirator with a replaceable mist/particulate filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances.
Eye Protection
Safety glasses with side shields, goggles or full-face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances i.e. methods of handling or engineering controls and according to risk assessments undertaken. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.
Hand Protection
Wear gloves of impervious material, such as PVC and neoprene. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.
Body Protection
Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. Industrial clothing should conform to the specifications detailed in AS/NZS 2919: Industrial clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Melting Point
Boiling Point
Solubility in Water
Specific Gravity
Vapour Pressure
Material Safety Data Sheet
Product Name DURAFLOOR X PRIMER HARDENER
Vapour Density
(Air=1)
Viscosity

Flash Point
Flammability
Auto-Ignition
Temperature
Flammable Limits -

Lower
Flammable Limits -

10. STABILITY AND REACTIVITY
Chemical Stability
Stable under normal conditions of storage and handling. When the base is mixed with the hardener an exothermic reaction starts (ie. heat is generated). If the mix is not applied within 20-30 minutes some smoking may occur.
Conditions to Avoid
Extremes of temperature and direct sunlight. Heat and other sources of ignition. Protect from freezing.
Incompatible
Peroxides, strong acids and strong oxidising agents.
Materials
Hazardous

Thermal decomposition may result in the release of toxic and/or irritating Decomposition
fumes and gases including carbon monoxide, carbon dioxide and oxides of Products
nitrogen. Ammonia produced when heated.
Hazardous Reactions Reaction with peroxides may result in violent decomposition of peroxide,
possibly creating an explosion. Slowly corrodes copper, aluminium and zinc.
Hazardous
Polymerization
11. TOXICOLOGICAL INFORMATION
Toxicology
Information
LD50 (Oral, Rat): 1500 mg/kg (estimate) LD50 (Dermal, Rabbit): >1000 mg/kg (estimate) Inhalation
Harmful by inhalation. Inhalation of product vapours may cause irritation of the nose, throat and respiratory system.
Ingestion
Harmful if swallowed. Ingestion of this product can cause irritation to the mouth, throat, oesophagus and stomach with symptoms of nausea, abdominal discomfort, vomiting and diarrhoea. Ingestion of this product will cause nausea, vomiting, abdominal pain and chemical burns to the mouth, throat and stomach.
Harmful in contact with skin. Product can be absorbed through skin with resultant toxic systemic effects. Causes burns. Corrosive to the skin. Skin contact can cause redness, itching, irritation, severe pain and chemical burns with resultant tissue destruction.
May cause sensitisation by skin contact.
Corrosive to eyes - contact can cause corneal burns. Contamination of eyes can result in permanent injury. Eye contact with vapour or liquid will cause stinging, blurring tearing, severe pain and possible permanent eye damage and blindness.
Chronic Effects
Prolonged or repeated skin contact may lead to allergic contact dermatitis and sensitisation in some individuals.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Persistence /
Degradability
Mobility

Environ. Protection
Do not discharge this material into waterways, drains and sewers.
Acute Toxicity - Fish
Isophorone diamine:LC50 (Leuciscus idus (fish)): 185 mg/L/48h Material Safety Data Sheet
Product Name DURAFLOOR X PRIMER HARDENER
Acute Toxicity -
13. DISPOSAL CONSIDERATIONS
Disposal
Do not allow into drains or watercourses or dispose of where ground or surface Considerations
waters may be affected. Wastes including emptied containers are controlled wastes and should be disposed of in accordance with all applicable local and national regulations.
14. TRANSPORT INFORMATION
Transport
This material is classified as a Class 8 (Corrosive Substances) Dangerous Information
Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition).
Class 8 Dangerous Goods are incompatible in a placard load with any of the following:- Class 1, Explosives- Division 4.3, Dangerous When Wet Substances- Division 5.1, Oxidising Agents- Division 5.2, Organic Peroxides- Class 6, Toxic or Infectious Substances, if the Class 6 dangerous goods are cyanides and the Class 8 dangerous goods are acids - Class 7, Radioactive Substancesand are incompatible with food and food packaging in any quantity.
Strong acids must not be loaded in the same freight container or on the same vehicle with strong alkalis. Packing Group I and II acids and alkalis should be considered as strong.
Marine Transport:Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea.
Air Transport:Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air.
U.N. Number
Proper Shipping
AMINES, LIQUID, CORROSIVE, N.O.S. - (CONTAINS ISOPHORONE DIAMINE AND Hazchem Code
Packing Group
EPG Number
IERG Number
15. REGULATORY INFORMATION
Regulatory
Classified as Hazardous according to criteria of National Occupational Health Information
& Safety Commission (NOHSC), Australia.
Classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Poisons Schedule
Hazard Category
16. OTHER INFORMATION
Date of preparation
or last revision of
MSDS
Contact

Person/Point
Material Safety Data Sheet
Product Name DURAFLOOR X PRIMER HARDENER
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Source: http://www.concreteplus.co.nz/public/pdfs/data-sheets/Durafloor-X-Primer-Hardener-SDS.pdf

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Thomas J. Maccarone Born August 26, 1974, Haverhill, Massachusetts, USAUniversity of SouthamptonSouthampton, HampshireCompact object populations, especially in globular clusters; accretion physics; time series analysisSouthampton, United Kingdom Reader in Astronomy (responsibilities and career track equivalent to associate professor in the Amer-ican nomenclature) Lecturer in Astronomy (re

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Los oxiuros son gusanos pequeños de color blanco que viven en los intestinos. Lasinfecciones por oxiuros son comunes en los niños pequeños y son fáciles de tratar. Si su niño está infectado por oxiuros el puede rascarse la cola con frecuencia. Ustedtambién puede notar que su niño se mueve mucho en la cama de noche o que no puededormir. La comezón es causada por el oxiuro hembra que sale

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